Synthetic approaches in oxynitride chemistry. (September 2018)

• Record Type: Journal Article
• Authors: Fuertes, Amparo
• Is Part Of: Progress in solid state chemistry. Volume 51(2018)
• Page Start: 63
• Page End: 70
• Publication Date: 2018-09
• Subjects: Oxynitrides -- Mixed anion oxides -- Anion order -- Ammonolysis -- High pressure synthesis -- Topochemical synthesis -- Perovskite oxynitrides -- Water splitting photocatalysis -- Oxynitride phosphors -- Dielectric materials -- Colossal magnetoresistance; Solid state chemistry -- Periodicals; Chimie de l'état solide -- Périodiques; 541.0421
• DOI: 10.1016/j.progsolidstchem.2017.11.001
• Languages: English
• ISSNs: 0079-6786

Abstract

Abstract: Mixed anion oxides are emerging materials showing a variety of physical and chemical properties. Among them oxynitrides are widely investigated because of notable photocatalytic, dielectric, luminescent and electronic properties. Nitrides show more positive free energies of formation than oxides because of the higher stability of N2 molecule with respect to O2 and the unfavourable electron affinity of nitrogen compared to oxygen. However the stability of oxynitrides is higher than for nitrides, and they easily form from oxides in presence of reactive gases as NH3 . In addition to ammonolysis several synthetic strategies have been developed in the last years leading to the stabilization of relevant materials with a variety of structures. In this review we will discuss recent progress in the synthesis of oxynitrides emphasizing the importance of kinetic factors and the influence of preparative parameters on the structure types and oxidation states of the cations, and the consequences on physical properties.