Influence of polymer reprocessing cycles on the microstructure and rheological behavior of polypropylene/mineral oil oleogels. (August 2015)

• Record Type: Journal Article
• Authors: Martín-Alfonso, J.E.; Franco, J.M.
• Is Part Of: Polymer testing. Volume 45(2015:Aug.)
• Page Start: 12
• Page End: 19
• Publication Date: 2015-08
• Subjects: Polypropylene -- Mineral oil -- Oleogels -- Reprocessing -- Degradation -- Viscoelastic properties; Polymers -- Testing -- Periodicals; Polymères -- Tests -- Périodiques; 620.1920287
• DOI: 10.1016/j.polymertesting.2015.04.016
• Languages: English
• ISSNs: 0142-9418

Abstract

Abstract: The overall objective of this work was to study the effect of reprocessing cycles of isotactic polypropylene (PP) on the rheological behavior and microstructure of gel-like dispersions in mineral oil. PP was subjected to 10 reprocessing cycles and oleogel samples were further prepared by using the mixing rheometry technique and characterized from a rheological point of view and polarized light optical microscopy (PLOM). Recycled polymer samples were also characterized by means of rheological measurements, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) to evaluate the property changes induced by reprocessing. The values of different linear viscoelastic functions (elastic modulus and complex viscosity) of recycled PP decrease with the number of reprocessing cycles, which influences oleogel rheological response. An empirical exponential correlation between the storage modulus (G′) of PP samples and the plateau modulus ( G N o ) of oleogels has been proposed to predict the rheological behavior of oleogels. Results were explained considering the scission of PP chains induced by the thermomechanical reprocessing treatment applied.