Synthesis and electrochemical properties of ordered mesoporous carbon supported well-dispersed cobalt oxide nanoparticles for supercapacitor. (April 2015)

• Record Type: Journal Article
• Authors: Zhao, Chunxia; Li, Junshen; Chen, Wen; Yang, Yunxia; Chiang, Ken; Burke, Nick
• Is Part Of: Materials research bulletin. Volume 64(2015:Apr.)
• Page Start: 55
• Page End: 60
• Publication Date: 2015-04
• Subjects: A. Nanostructures -- A. Composites -- C. Electron microscopy -- D. Electrochemical properties; Materials -- Periodicals; Crystal growth -- Periodicals; Matériaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Crystal growth; Materials; Periodicals; 620.11
• DOI: 10.1016/j.materresbull.2014.12.047
• Languages: English
• ISSNs: 0025-5408

Abstract

Graphical abstract: Highlights: Well-dispersed cobalt oxide nanoparticles with uniform size were loaded into CMK-3. The composites were synthesized by impregnation method with post ammonia treatment. The composites possess high specific surface area over 1000 m 2 /g. The composites exhibit important EDLC and pseudocapacitance. The pseudocapacitive fraction of 12.7CoO@C-400 is up to 524.8 F/g. Abstract: Recent progress in porous carbons incorporated with guest metal oxide nanoparticles has attracted huge attention in energy-related area. Well-dispersed cobalt oxide nanoparticles supported on ordered mesoporous carbon have been synthesized under impregnation conditions with post ammonia treatment. The composites have not only retained ordered mesoporous structure of the carbon support with high specific surface area over 1000 m 2 /g, but also shown a good control of cobalt oxide nanoparticles dispersion with uniform size. The well-retained mesoporous structure helps to facilitate the ion diffusion and then contribute electric double-layer capacitance. The cobalt oxide nanoparticle loading contributes important pseudocapacitance associated with Faradic charge transfer reactions between the cobalt oxides and the electrolyte. The composites loaded with 12.7 wt% cobalt oxide nanoparticles possess significant pseudocapacitance fraction of 524.8 F/g.