Na1.5La1.5TeO6: Na+ conduction in a novel Na-rich double perovskite. Issue 72 (3rd August 2018)

• Record Type: Journal Article
• Authors: Amores, Marco; Baker, Peter J.; Cussen, Edmund J.; Corr, Serena A.
• Is Part Of: Chemical communications. Volume 54:Issue 72(2018)
• Page Start: 10040
• Page End: 10043
• Publication Date: 2018-08-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc03367f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A novel Na-rich double perovskite, Na1.5 La1.5 TeO6, is reported. The transport properties, explored at the macroscopic and local level, reveal a low activation energy barrier for Na + diffusion and great promise for use as an electrolyte for all solid-state Na-batteries. Abstract : Increasing demand for lithium batteries for automotive applications, coupled with the necessity to move to large-scale energy storage systems, is driving a push towards new technologies and has seen Na-ion batteries emerge as a leading alternative to Li-ion. Amongst these, all solid-state configurations represent a promising route to achieving higher energy densities and increased safety. Remaining challenges include the need for Na + solid electrolytes with the requisite ionic conductivities crucial for use in a solid-state cell. Here, we present the novel Na-rich double perovskite, Na1.5 La1.5 TeO6 . The transport properties, explored at the macroscopic and local level, reveal a low activation energy barrier for Na + diffusion and great promise for use as an electrolyte for all solid-state Na-batteries.