Bifunctional Zinc Oxide Nanoburger Aggregates as the Dye-Adsorption and Light-Scattering Layer for Dye-Sensitized Solar Cells. (1st July 2015)

• Record Type: Journal Article
• Authors: Chang, Wei-Chen; Lin, Lu-Yin; Yu, Wan-Chin
• Is Part Of: Electrochimica acta. Volume 169(2015)
• Page Start: 456
• Page End: 461
• Publication Date: 2015-07-01
• Subjects: Aggregate -- Dye–sensitized solar cell -- Electrochemical impedance spectroscopy -- Photoanode -- Zinc oxide; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.04.056
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Highlights: Novel ZnO aggregate nanoburgers are made using a low temperature aqueous solution. ZnO nanoburgersare formed with two burger bodies comprisesmall nanocrystalline. ZnO nanoburgers have higher dye loading and better light scattering ability. ZnO nanoburgers dye-sensitized solar cell attain a conversion efficiency of 4.03%. Low temperature annealing (<150 °C) of ZnO film is benefit topolymeric substrate. Abstract: A novel burger-like aggregate nanostructure assembled from ZnO nanocrystals was synthesized by using a simple aqueous solution method at a low temperature (80 °C). The burger-shaped nanostructure consists of two bun-like exterior layers joined together via a disk-shaped middle layer. Each exterior layer has a thickness of 200 to 300 nm and a diameter of 400 to 600 nm, while the relatively small middle layer has a thickness of 20 to 50 nm and a diameter approximately 80 nm smaller than the exterior layer. The nanoburger-based dye-sensitized solar cells (DSSCs) achieved a higher light-to-electricity conversion efficiency of 4.03% than those made of commercial ZnO nanoparticles (3.07%). The superior photovoltaic performance of the nanoburger-based DSSCs can be ascribed primarily to the enhanced dye adsorption ability of the aggregates. Because of their submicron sizes, the burger-like aggregates may also generate prominent light scattering, thereby improving the photoanode's optical absorption. Furthermore, the low-temperature heat-treatment process (150 °C) used to fabricate the photoanode film provides opportunities to utilize polymeric substrates in flexible DSSCs.