A stereogenic heteroatom-containing substituent as an inducer of chirality in the derivatives of thiophenes (mono, oligo, and poly), fullerenes C60, and multiwalled nanotubes. (1st February 2016)

• Record Type: Journal Article
• Authors: Krasowska, Dorota; Zajac, Adrian; Wach, Paulina; Ciesielski, Wojciech; Michalski, Oskar; Kulawik, Damian; Pyzalska, Magdalena; Dudzinski, Bogdan; Pokora-Sobczak, Patrycja; Makowski, Tomasz; Janicka, Magdalena
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 191:Number 2(2016)
• Page Start: 211
• Page End: 219
• Publication Date: 2016-02-01
• Subjects: Mono and polythiophenes -- multiwalled carbon nanotubes (MWCNT) -- fullerene C60 derivatives -- chirality -- polymerization; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2015.1079198
• Languages: English
• ISSNs: 1042-6507

Abstract

GRAPHICAL ABSTRACT: Abstract: Synthetic procedures applied recently in our laboratory for the preparation of a new thiophene, fullerene C60 and multiwalled carbon nanotube (MWCNT) derivatives functionalized with a substituent containing an achiral and/or a stereogenic heteroatom are reviewed. Polymerization reactions of selected optically active 2-(3′-thienyl)ethyl aryl(alkyl) sulfoxides and tert -butyl-[2-(3′-thienyl)ethyl]phenylphosphine oxide are also mentioned. Mechanistic and stereochemical aspects of the presented protocols are discussed.