Direct C–N bond formation in an in situ ligand transformation reaction and formation of polymeric 1D cadmium(II) complexes with end-to-end bridging thiocyanate or selenocyanate ions: Synthesis, structures and theoretical studies. (5th September 2017)

• Record Type: Journal Article
• Authors: Sadhu, Mehul H.; Solanki, Ankita; Kundu, T.; Hingu, Vinayak; Ganguly, B.; Kumar, Sujit B.
• Is Part Of: Polyhedron. Volume 133(2017)
• Page Start: 8
• Page End: 15
• Publication Date: 2017-09-05
• Subjects: Cd(II) complexes -- NCS/SeCN ion -- End-to-end bridge -- 1D chain -- DFT; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2017.05.007
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical abstract: Two new one-dimensional polymeric thiocyanato and selenocyanato bridged cadmium(II) complexes [Cd(dpip)(μ1, 3 -SCN)2 ] n and [Cd(dpip)(μ1, 3 -SeCN)2 ] n, where dpip = 3, 5-dimethyl-1-((3-phenylimidazolidin-1-yl)-methyl)-1H-pyrazole) have been synthesized and characterized. The bidentate N2 -coordinated ligand dpip is formed from N4 -coordinated tetradentate ligand N, N -bis(3, 5-dimethyl-1H-pyrazol-1-yl)methyl-N2 -phenylethane-1, 2-diamine (bdpab) during in situ complexation reaction. The 1D structures of the two complexes show each cadmium(II) center has distorted octahedral geometry and both NCS − and NCSe − act as end-to-end (µ-1, 3) bridging ligands. The DFT calculations performed with the two complexes corroborated the observed crystal structures and the structural parameters were found to be in good agreement in both calculated and X-ray geometries. Abstract: Two new one-dimensional polymeric thiocyanato and selenocyanato bridged cadmium(II) complexes [Cd(dpip)(μ1, 3 -SCN)2 ] n and [Cd(dpip)(μ1, 3 -SeCN)2 ] n, where dpip = 3, 5-dimethyl-1-((3-phenylimidazolidin-1-yl)-methyl)-1H-pyrazole have been synthesized and characterized by elemental analysis, IR, 1 H NMR and single crystal X-ray diffraction studies. The bidentate N2 -coordinated ligand dpip is formed from N4 -coordinated tetradentate ligand N, N -bis(3, 5-dimethyl-1H-pyrazol-1-yl)methyl-N2 -phenylethane-1, 2-diamine (bdpab) due to unusual transformation, removing one pyrazole group and formation of saturated imidazole ring during in situ complexation reaction. The 1D structures of the two complexes have been confirmed by single crystal X-ray diffraction studies and both NCS − and NCSe − act as end-to-end (µ-1, 3) bridging ligands. The coordination environment around the cadmium center in the complexes are CdN4 S2 and CdN4 Se2, respectively and each cadmium(II) center has distorted octahedral geometry. The distortion in the molecules are due to two unequal Cd–N (organic ligand dpip) bond lengths and small bite angel of the unsymmetrical organic ligand. The DFT calculations performed with cadmium(II) complexes [Cd(dpip)(μ1, 3 -SCN)2 ] n and [Cd(dpip)(μ1, 3 -SeCN)2 ] n corroborated the observed crystal structures and the structural parameter were found to be in good agreement in both calculated and X-ray geometries.