Transformations of terpenes and terpenoids via carbon–carbon double bond metathesis. Issue 16 (31st July 2018)

• Record Type: Journal Article
• Authors: Bruneau, Christian; Fischmeister, Cédric; Mandelli, Dalmo; Carvalho, Wagner A.; dos Santos, Eduardo N.; Dixneuf, Pierre H.; Sarmento Fernandes, Luciana
• Is Part Of: Catalysis science & technology. Volume 8:Issue 16(2018)
• Page Start: 3989
• Page End: 4004
• Publication Date: 2018-07-31
• Subjects: Catalysis -- Periodicals; 541.395
• DOI: 10.1039/c8cy01152d
• Languages: English
• ISSNs: 2044-4753

Abstract

Abstract : The review reports on transformations of unsaturated terpenes and terpenoids via olefin metathesis processes including ring closing metathesis of dienes, cross metathesis with functional olefins and ethenolysis, and ring opening metathesis as well as ring opening/cross metathesis. Abstract : Stimulated by the strong interest in replacing fossil raw materials by renewable feedstocks in chemical industry, alkene metathesis of unsaturated bio-sourced olefins has been recently investigated with the objective of producing high-value molecules using green and atom economic strategies. It is due time to review what has been achieved in this field using terpenes and terpenoids as olefin metathesis partners. These substrates, derived from the isoprene structure, present different types of carbon–carbon double bonds that can be involved in self metathesis, ring closing metathesis, cross metathesis including ethenolysis, and ring opening metathesis. The successful achievements and remaining bottlenecks in this field will be discussed.