Strong light–matter interaction in tungsten disulfide nanotubes. Issue 32 (13th July 2018)

• Record Type: Journal Article
• Authors: Yadgarov, Lena; Višić, Bojana; Abir, Tsafrir; Tenne, Ron; Polyakov, Alexander Yu.; Levi, Roi; Dolgova, Tatyana V.; Zubyuk, Varvara V.; Fedyanin, Andrey A.; Goodilin, Eugene A.; Ellenbogen, Tal; Tenne, Reshef; Oron, Dan
• Is Part Of: Physical chemistry chemical physics. Volume 20:Issue 32(2018)
• Page Start: 20812
• Page End: 20820
• Publication Date: 2018-07-13
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c8cp02245c
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : The WS2 nanotubes emerge as novel class of polaritonic quasi 1D-material by sustaining excitons coupled with tunable cavity modes. Abstract : Transition metal dichalcogenide materials have recently been shown to exhibit a variety of intriguing optical and electronic phenomena. Focusing on the optical properties of semiconducting WS2 nanotubes, we show here that these nanostructures exhibit strong light–matter interaction and form exciton–polaritons. Namely, these nanotubes act as quasi 1-D polaritonic nano-systems and sustain both excitonic features and cavity modes in the visible-near infrared range. This ability to confine light to subwavelength dimensions under ambient conditions is induced by the high refractive index of tungsten disulfide. Using "finite-difference time-domain" (FDTD) simulations we investigate the interactions between the excitons and the cavity mode and their effect on the extinction spectrum of these nanostructures. The results of FDTD simulations agree well with the experimental findings as well as with a phenomenological coupled oscillator model which suggests a high Rabi splitting of ∼280 meV. These findings open up possibilities for developing new concepts in nanotube-based photonic devices.