Carbazole/α-carboline hybrid bipolar compounds as electron acceptors in exciplex or non-exciplex mixed cohosts and exciplex-TADF emitters for high-efficiency OLEDs. Issue 32 (3rd August 2018)

• Record Type: Journal Article
• Authors: Wu, Qingjing; Wang, Menghan; Cao, Xudong; Zhang, Di; Sun, Ning; Wan, Shigang; Tao, Youtian
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 32(2018)
• Page Start: 8784
• Page End: 8792
• Publication Date: 2018-08-03
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8tc02353k
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Electron acceptors based on the electron-deficient carboline of CbPyCN exhibited better electroluminescence performance than CzPyCN in exciplex or non-exciplex mixed cohosts and exciplex-emitters. Abstract : Two cyanopyridine derivatives CzPyCN and CbPyCN are designed and synthesized through a simple catalyst free aromatic nucleophilic substitution reaction by using 2-cyano-3, 5-difluoropyridine as the electrophile and carbazole (Cz) or α-carboline (Cb) as the nucleophile. CbPyCN exhibits blue-shifted emission ( λ max at 420 nm), a wider optical band-bap ( E g : 3.22 eV) and a higher triplet energy ( E T : 2.79 eV) than CzPyCN (454 nm, 3.02 and 2.69 eV). The HOMO/LUMO energy levels were −5.77/−2.75 and −5.58/−2.38 eV for CzPyCN and CbPyCN, respectively. With enough HOMO/LUMO energy level offsets, CzPyCN and CbPyCN could function as electron acceptors to form an exciplex with a typical electron-donor, di-[4-( N, N -ditolyl-amino)-phenyl]cyclohexane (TAPC), showing broad exciplex emission with peaks at 530 and 520 nm, and long decay lifetimes of 1097 and 1014 ns, respectively. However, when mixed with 1, 3-di(9 H -carbazol-9-yl)-benzene (mCP), no exciplex but only typical CzPyCN or CbPyCN deep blue emission with a decay lifetime of 14.3 or 12.1 ns is observed. Blue phosphorescent OLEDs by using mCP (TAPC)/CzPyCN as mixed cohosts show a maximum EQE of 19.1 (6.2)%, lower than the 21.4 (13.3)% of mCP (TAPC)/CbPyCN, respectively, which is probably due to the better electron-transport properties and higher triplet energy levels for electron-deficient α-carboline containing CbPyCN. Similarly, exciplex-type green fluorescent OLEDs based on TAPC/CzPyCN show a lower maximum efficiency of 22.0 cd A −1 and 7.4% than 27.5 cd A −1 and 9.1% of TAPC/CbPyCN.