Post-functionalization of a photoactive hybrid polyoxotungstate. Issue 31 (17th May 2018)

• Record Type: Journal Article
• Authors: Cameron, Jamie M.; Fujimoto, Satomi; Wei, Rong-Jia; Newton, Graham N.; Oshio, Hiroki
• Is Part Of: Dalton transactions. Volume 47:Issue 31(2018)
• Page Start: 10590
• Page End: 10594
• Publication Date: 2018-05-17
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt01253a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A new approach to the development of photoactive hybrid polyoxometalates is reported, combining inorganic and organic functionalisation strategies. Abstract : A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.