One pot preparation of α-dithioacetal/α-diselenoacetal amides via a dual-C–S/C–Se bond formation and C–C bond cleavage cascade of 3-oxo-butanamides12. Issue 15 (27th June 2018)

• Record Type: Journal Article
• Authors: Zou, Jiao-xia; Wang, Yong-qiang; Huang, Long-tao; Jiang, Yi; Chen, Jin-hong; Zhu, Long-qing; Yang, Yu-hang; Feng, Yi-yue; Peng, Xue; Wang, Zhen
• Is Part Of: Organic chemistry frontiers. Volume 5:Issue 15(2018)
• Page Start: 2317
• Page End: 2321
• Publication Date: 2018-06-27
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c8qo00435h
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : A new and practical approach to α-dithioacetal/α-diselenoacetal amides has been developed. Abstract : A new and practical approach to α-dithioacetal/α-diselenoacetal amides has been developed, combining sequential functionalization of amides and a C–C bond cleavage strategy. In this reaction, various α-dithioacetal/α-diselenoacetal amides from 3-oxo-butanamides were prepared in one step with good regioselectivity and functional group tolerance.