Metallic Adhesive Layers for Ag‐Based First Surface Mirrors. Issue 7 (24th March 2018)

• Record Type: Journal Article
• Authors: James, Robin A.; Stapleton, Andrew J.; Hughes, Adam; Charrault, Eric; Zuber, Kamil; Switalska, Eliza; Evans, Drew; Murphy, Peter; Llusca, Marta
• Is Part Of: Advanced engineering materials. Volume 20:Issue 7(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-03-24
• Subjects: adhesion -- first surface mirrors -- high reflectivity -- seed layer -- silver; Materials -- Periodicals; 620.11
• DOI: 10.1002/adem.201800106
• Languages: English
• ISSNs: 1438-1656

Abstract

Abstract : Metallic thin films have been evaluated as adhesive layers for first surface mirrors. Thin films (0.5–4 nm thick) of Cr, Cu, Ge, Sn, and Ni, capped with an over layer of 100 nm of Ag have been deposited by means of ion assisted electron beam evaporation onto glass substrates. The specular reflectance, conductivity, morphology, adhesion, and abrasion resistance of the mirrors have been assessed and compared. This work demonstrates the superior Ni and Ge adhesion and abrasion resistance to Ag thin films, while Cr and again Ni are the best candidates in terms of reflectance enhancement. In particular, 4 nm of Ni increases the Ag reflectance from 95.7% to 96.7%, exhibits the strongest adhesion as determined by the cross hatch tape test and the lowest loss of material after the different abrasion tests is just 50% in comparison to 100% for Ag‐coated glass substrates. Abstract : This paper evaluates Cr, Cu, Ge, Sn, and Ni thin films as adhesive layers for Ag‐based first surface mirrors. Ni, 4 nm thick, increases the Ag reflectance from 95.7% to 96.7%, exhibits the strongest adhesion and the lowest loss of material after the abrasion tests which is just 50% in comparison to 100% for Ag‐coated glass substrates.