Engineering a Cu‐MOF Nano‐Catalyst by using Post‐Synthetic Modification for the Preparation of 5‐Substituted 1H‐Tetrazoles. (20th June 2018)

• Record Type: Journal Article
• Authors: Salahshournia, Behrang; Hamadi, Hosein; Nobakht, Valiollah
• Is Part Of: Applied organometallic chemistry. Volume 32:Number 8(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-06-20
• Subjects: [3 + 2] cycloaddition reaction -- 5‐substituted‐1H‐tetrazoles -- metal‐exchange -- MOF -- transmetalation; Organometallic chemistry -- Periodicals; Organometallic compounds -- Periodicals; 547.05
• DOI: 10.1002/aoc.4416
• Languages: English
• ISSNs: 0268-2605

Abstract

Abstract : A new nano scale Cu‐MOF has been obtained via post‐synthetic metalation by immersing a Zn‐MOF as a template in DMF solutions of copper(II) salts. The Cu‐MOF serves as recyclable nano‐catalyst for the preparation of 5‐substituted 1 H ‐tetrazoles via [3 + 2] cycloaddition reaction of various nitriles and sodium azide in a green medium (PEG). The post‐synthetic metalated MOF were characterized by FT‐IR spectroscopy, powder X‐ray diffraction (PXRD), atomic absorption spectroscopy (AAS), and energy dispersive X‐ray spectroscopy (EDX) techniques. The morphology and size of the nano‐catalyst were determined by field emission scanning electron microscopy (FE‐SEM). Abstract : A new nano‐scale Cu‐MOF has been obtained via post‐synthetic metalation by immersing a Zn‐MOF as a template in DMF solutions of copper (II) salts which serves as an efficient catalyst for the preparation of 5‐substituted 1H‐tetrazoles.