Merging visible-light photoredox and micellar catalysis: arylation reactions with anilines nitrosated in situ. Issue 15 (5th July 2018)

• Record Type: Journal Article
• Authors: Bu, Mei-jie; Lu, Guo-ping; Jiang, Jianzhong; Cai, Chun
• Is Part Of: Catalysis science & technology. Volume 8:Issue 15(2018)
• Page Start: 3728
• Page End: 3732
• Publication Date: 2018-07-05
• Subjects: Catalysis -- Periodicals; 541.395
• DOI: 10.1039/c8cy01221k
• Languages: English
• ISSNs: 2044-4753

Abstract

Abstract : A micellar photocatalytic system has been disclosed, which enables arylation reactions with anilines nitrosated in situ to run in water. Abstract : An aqueous photocatalytic system was designed by merging visible-light photoredox catalysis with micellar catalysis. Eosin B, an organic dye, was utilized as the photocatalyst, and Triton X-100 was employed as the surfactant; both are inexpensive and commercially available. This clean and energy-saving catalytic system enables photocatalytic reactions of the diazonium ion generated in situ to proceed smoothly in water without any co-solvents or additives at room temperature.