Iron(ii) coordination polymer catalysed hydroboration of ketones. Issue 29 (5th July 2018)

• Record Type: Journal Article
• Authors: Li, Li; Liu, E; Cheng, Jessica; Zhang, Guoqi
• Is Part Of: Dalton transactions. Volume 47:Issue 29(2018)
• Page Start: 9579
• Page End: 9584
• Publication Date: 2018-07-05
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt02134a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Catalytic hydroboration of ketones with pinacolborane was achieved using a two-dimensional iron(ii ) coordination polymer based on a divergent 4, 2′;6′, 4′′-terpyridine ligand. Abstract : Catalytic hydroboration of ketones with pinacolborane was achieved with a 2D iron(ii ) coordination polymer (CP) of a divergent 4, 2′;6′, 4′′-terpyridine (tpy) derivative under mild conditions with high efficiency. This solid iron catalyst system is more active towards the hydroboration of ketones than that of aldehydes, displaying a different trend of reactivity from known homogeneous iron hydroboration catalysts.