1, 4‐Iron Migration for Expedient Allene Annulations through Iron‐Catalyzed C−H/N−H/C−O/C−H Functionalizations. (30th May 2018)
- Record Type:
- Journal Article
- Title:
- 1, 4‐Iron Migration for Expedient Allene Annulations through Iron‐Catalyzed C−H/N−H/C−O/C−H Functionalizations. (30th May 2018)
- Main Title:
- 1, 4‐Iron Migration for Expedient Allene Annulations through Iron‐Catalyzed C−H/N−H/C−O/C−H Functionalizations
- Authors:
- Mo, Jiayu
Müller, Thomas
Oliveira, João C. A.
Ackermann, Lutz - Abstract:
- Abstract: C−H activation bears great potential for enabling sustainable molecular syntheses in a step‐ and atom‐economical manner, with major advances having been realized with precious 4d and 5d transition metals. In contrast, we employed earth abundant, nontoxic iron catalysts for versatile allene annulations through a unique C−H/N−H/C−O/C−H functionalization sequence. The powerful iron catalysis occurred under external‐oxidant‐free conditions even at room temperature, while detailed mechanistic studies revealed an unprecedented 1, 4‐iron migration regime for facile C−H activations.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 26(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 26(2018)
- Issue Display:
- Volume 130, Issue 26 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 26
- Issue Sort Value:
- 2018-0130-0026-0000
- Page Start:
- 7845
- Page End:
- 7849
- Publication Date:
- 2018-05-30
- Subjects:
- Allene -- C-H-Aktivierungen -- Eisen -- Gruppenverschiebungen -- Redoxneutrale Reaktionen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201801324 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 6973.xml