A three body problem: a genuine heterotrimetallic molecule vs. a mixture of two parent heterobimetallic molecules. Issue 21 (18th May 2018)

• Record Type: Journal Article
• Authors: Han, Haixiang; Wei, Zheng; Barry, Matthew C.; Carozza, Jesse C.; Alkan, Melisa; Rogachev, Andrey Yu; Filatov, Alexander S.; Abakumov, Artem M.; Dikarev, Evgeny V.
• Is Part Of: Chemical science. Volume 9:Issue 21(2018)
• Page Start: 4736
• Page End: 4745
• Publication Date: 2018-05-18
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c8sc00917a
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : Tetranuclear molecular precursor Li2 CoNiL6 for oxide cathode materials has been shown to contain hetero tri metallic and both parent hetero bi metallic molecules. Abstract : This work raises a fundamental question about the "real" structure of molecular compounds containing three different metals: whether they consist of genuine hetero tri metallic species or of a mixture of parent hetero bi metallic species. Heterotrimetallic complex Li2 CoNi(tbaoac)6 (1, tbaoac = tert -butyl acetoacetate) has been designed based on the model tetranuclear structure featuring two transition metal sites in order to be utilized as a molecular precursor for the low-temperature preparation of the LiCo0.5 Ni0.5 O2 battery cathode material. An investigation of the structure of1 appeared to be very challenging, since the Co and Ni atoms have very similar atomic numbers, monoisotopic masses, and radii as well as the same oxidation state and coordination number/environment. Using a statistical analysis of heavily overlaid isotope distribution patterns of the [Li2 MM′L5 ] + (M/M′ = Co2, Ni2, and CoNi) ions in DART mass spectra, it was concluded that the reaction product1 contains both heterotrimetallic and bimetallic species. A structural analogue approach has been applied to obtain Li2 MMg(tbaoac)6 (M = Co (2 ) and Ni (3 )) complexes that contain lighter, diamagnetic magnesium in the place of one of the 3d transition metals. X-ray crystallography, mass spectrometry, and NMR spectroscopy unambiguously confirmed the presence of three types of molecules in the reaction mixture that reaches an equilibrium, Li2 M2 L6 + Li2 Mg2 L6 ↔ 2Li2 MMgL6, upon prolonged reflux in solution. The equilibrium mixture was shown to have a nearly statistical distribution of the three molecules, and this is fully supported by the results of theoretical calculations revealing that the stabilization energies of hetero tri metallic assemblies fall exactly in between those for the parent hetero bi metallic species. The LiCo0.5 Ni0.5 O2 quaternary oxide has been obtained in its phase-pure form by thermal decomposition of heterometallic precursor1 at temperatures as low as 450 °C. Its chemical composition, structure, morphology, and transition metal distribution have been studied by X-ray and electron diffraction techniques and compositional energy-dispersive X-ray mapping with nanometer resolution. The work clearly illustrates the advantages of heterometallic single-source precursors over the corresponding multi-source precursors.