Ion Imprinted Polymer for Preconcentration and Determination of Ultra-Trace Cadmium, Employing Flow Injection Analysis with Thermo Spray Flame Furnace Atomic Absorption Spectrometry. Issue 11 (November 2016)

• Record Type: Journal Article
• Authors: do Lago, Ayla Campos; Marchioni, Camila; Mendes, Tássia Venga; Wisniewski, Célio; Fadini, Pedro Sergio; Luccas, Pedro Orival
• Is Part Of: Applied spectroscopy. Volume 70:Issue 11(2016)
• Page Start: 1842
• Page End: 1850
• Publication Date: 2016-11
• Subjects: Cadmium -- Ion imprinted polymer -- thermospray flame furnace atomic absorption spectrometry (TS-FF-AAS) -- flow injection analysis (FIA); Spectrum analysis -- Periodicals; 543.505
• DOI: 10.1177/0003702816658669
• Languages: English
• ISSNs: 0003-7028

Abstract

This work proposes a preconcentration method using an ion imprinted polymer (IIP) for determination of cadmium, in several samples, employing a mini-column filled with the polymer coupled into a flow injection analysis system with detection by thermospray flame furnace atomic absorption spectrometry (FIA-TS-FF-AAS). The polymer was synthesized via bulk using methacrylic acid and vinylimidazole as a functional monomer. For the FIA system initial assessment, the variables: pH, eluent concentration and buffer concentration were studied, employing a 23 full factorial design. To obtain the optimum values for each significant variable, a Doehlert matrix was employed. After the optimization conditions as: pH 5.8, eluent (HNO3) concentration of 0.48 mol L −1 and buffer concentration of 0.01 mol L −1, were adopted. The proposed method showed a linear response in the range of 0.081–10.0 μg L −1, limits detection and quantification of 0.024 and 0.081 μg L −1, respectively; preconcentration factor of 165, consumptive index of 0.06 mL, concentration efficiency 132 min −1, and frequency of readings equal to 26 readings h −1 . The accuracy was checked by analysis of certified reference materials for trace metals and recovery tests. The obtained results were in agreement with 95% confidence level (t-test). The method was adequate to apply in samples of: jewelry (earrings) (2.38 ± 0.28 μg kg −1 ), black tea (1.09 ± 0.15 μg kg −1 ), green tea (3.85 ± 0.13 μg kg −1 ), cigarette tobacco (38.27 ± 0.22 μg kg −1 ), and hair (0.35 ± 0.02 μg kg −1 ).