Recyclable cellulose-palladium nanoparticles for clean cross-coupling chemistry. Issue 15 (29th March 2018)

• Record Type: Journal Article
• Authors: Lu, Zhichao; Jasinski, Jacek B.; Handa, Sachin; Hammond, Gerald B.
• Is Part Of: Organic & biomolecular chemistry. Volume 16:Issue 15(2018)
• Page Start: 2748
• Page End: 2752
• Publication Date: 2018-03-29
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c8ob00527c
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : Cheap, recyclable, and robust cellulose-palladium nanoparticles were developed and fully characterized by FTIR, TEM, XPS, TGA, and NMR. Abstract : Cheap, recyclable, and robust cellulose-palladium nanoparticles were developed and fully characterized by FTIR, TEM, XPS, TGA, and NMR. The nanoparticles enabled cross-coupling chemistry in a truly general fashion i.e., Suzuki–Miyaura, Heck, Sonogashira, and C–H activation. Notably, all types of transformations were achieved with a single type of nanocatalyst. Complete recyclability of the catalyst and low traces of palladium in the product demonstrates the greenness of the protocol.