A luminescent [Pd4Ru8]24+ supramolecular cage12. Issue 47 (25th May 2018)

• Record Type: Journal Article
• Authors: Rota Martir, Diego; Cordes, David B.; Slawin, Alexandra M. Z.; Escudero, Daniel; Jacquemin, Denis; Warriner, Stuart L.; Zysman-Colman, Eli
• Is Part Of: Chemical communications. Volume 54:Issue 47(2018)
• Page Start: 6016
• Page End: 6019
• Publication Date: 2018-05-25
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc02104j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A phosphorescent cage of the form [Pd4 Ru8 ] 24+ is reported. Abstract : A phosphorescent cage of the form [Pd4 Ru8 ] 24+ is reported. The cage was formed using the metalloligand [Ru(d t bubpy)2 (qpy)] 2+, where qpy = 4, 4′:2′, 2′′:4′′, 4′′′-quaterpyridine and d t bubpy = 4, 4′-di- tert -butyl-2, 2′-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.