Stabilities of byströmite, MgSb2O6, ordoñezite, ZnSb2O6 and rosiaite, PbSb2O6, and their possible roles in limiting antimony mobility in the supergene zone. (2nd January 2018)

• Record Type: Journal Article
• Authors: Roper, Adam J.; Leverett, Peter; Murphy, Timothy D.; Williams, Peter A.
• Is Part Of: Mineralogical magazine. Volume 79:Number 3(2015:Jun.)
• Page Start: 537
• Page End: 544
• Publication Date: 2018-01-02
• Subjects: byströmite, -- ordoñezite, -- rosiaite, -- antimony, -- solubility, -- mobility, -- chemical mineralogy, -- supergene zone; Mineralogy -- Periodicals; Mineralogy -- Great Britain -- Periodicals; 549.05
• DOI: 10.1180/minmag.2015.079.3.03
• Languages: English
• ISSNs: 0026-461X

Abstract

Abstract: In order to clarify the roles that secondary minerals may have in determining the extent of dispersion of Sb in the supergene environment, syntheses and stability studies of the Sb(V) oxides byströmite, MgSb2 O6, ordoñezite, ZnSb2 O6 and rosiaite, PbSb2 O6, have been undertaken. Solubilities in aqueous HNO3 were determined at 298.2 K and the data obtained used to calculate values of Δ at the same temperature. The derived Δ (s, 298.2 K) values for MgSb2 O6 (–1554.1 ±3.6 kJ mol –1 ), ZnSb2 O6 (–1257.0 ±2.6 kJ mol –1 ) and PbSb2 O6 (–1154.2 ±2.6 kJ mol –1 ) have been used in subsequent calculations to determine their relative stabilities and relationships with other secondary Sb minerals.