(2-Fluoroallyl)boronates: new reagents for diastereoselective 2-fluoroallylboration of aldehydes. Issue 27 (27th June 2018)
- Record Type:
- Journal Article
- Title:
- (2-Fluoroallyl)boronates: new reagents for diastereoselective 2-fluoroallylboration of aldehydes. Issue 27 (27th June 2018)
- Main Title:
- (2-Fluoroallyl)boronates: new reagents for diastereoselective 2-fluoroallylboration of aldehydes
- Authors:
- Novikov, Maxim A.
Nefedov, Oleg M. - Abstract:
- Abstract : New reagents for anti -selective 2-fluoroallylboration of aromatic and aliphatic aldehydes—(2-fluoroallyl)pinacolboranes, were prepared by Pd-catalyzed borylation of 2-fluoroallyl chlorides. Abstract : A Pd-catalyzed borylation of 2-fluoroallyl chlorides with B2 pin2 in the presence of [(2-MeAll)PdCl]2 /TMEDA or [(2-MeAll)Pd(IPr)Cl] was developed to afford (2-fluoroallyl)pinacolboronates with high Z -selectivity. The products proved to be useful for anti -selective 2-fluoroallylboration of aromatic and aliphatic aldehydes.
- Is Part Of:
- Organic & biomolecular chemistry. Volume 16:Issue 27(2018)
- Journal:
- Organic & biomolecular chemistry
- Issue:
- Volume 16:Issue 27(2018)
- Issue Display:
- Volume 16, Issue 27 (2018)
- Year:
- 2018
- Volume:
- 16
- Issue:
- 27
- Issue Sort Value:
- 2018-0016-0027-0000
- Page Start:
- 4963
- Page End:
- 4967
- Publication Date:
- 2018-06-27
- Subjects:
- Chemistry, Organic -- Periodicals
Bioorganic chemistry -- Periodicals
Chemistry, Physical organic -- Periodicals
547 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/ob#!recentarticles&all ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8ob01103f ↗
- Languages:
- English
- ISSNs:
- 1477-0520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6286.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 6963.xml