An arene-tethered silylene ligand enabling reversible dinitrogen binding to iron and catalytic silylation. Issue 58 (5th July 2018)
- Record Type:
- Journal Article
- Title:
- An arene-tethered silylene ligand enabling reversible dinitrogen binding to iron and catalytic silylation. Issue 58 (5th July 2018)
- Main Title:
- An arene-tethered silylene ligand enabling reversible dinitrogen binding to iron and catalytic silylation
- Authors:
- Bai, Yunping
Zhang, Jianying
Cui, Chunming - Abstract:
- Abstract : A silylene–iron(0) dinitrogen complex enabled the catalytic silylation of N2 with high activity. Abstract : An arene-tethered silylene ligand, L (L = PhC( t BuN)2 SiCH2 C( t Bu)NAr, Ar = 2, 6- i Pr2 C6 H3 ), allowed the synthesis of three-coordinate Fe(ii ) silylamido and piano-stool Fe(0) dinitrogen complexes LFe[N(SiMe3 )2 ]2 (3 ) and LFe-N2 (4 ), which not only exhibit interesting bonding but also enabled the catalytic silylation of N2 to yield N(SiMe3 )3 under 1 atm of N2 at room temperature with high TONs.
- Is Part Of:
- Chemical communications. Volume 54:Issue 58(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 58(2018)
- Issue Display:
- Volume 54, Issue 58 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 58
- Issue Sort Value:
- 2018-0054-0058-0000
- Page Start:
- 8124
- Page End:
- 8127
- Publication Date:
- 2018-07-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc03734e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 6964.xml