A manganese porphyrin–α-cyclodextrin conjugate as an artificial enzyme for the catalytic epoxidation of polybutadiene. Issue 44 (16th May 2018)
- Record Type:
- Journal Article
- Title:
- A manganese porphyrin–α-cyclodextrin conjugate as an artificial enzyme for the catalytic epoxidation of polybutadiene. Issue 44 (16th May 2018)
- Main Title:
- A manganese porphyrin–α-cyclodextrin conjugate as an artificial enzyme for the catalytic epoxidation of polybutadiene
- Authors:
- Zhang, Qi-Wei
Elemans, Johannes A. A. W.
White, Paul B.
Nolte, Roeland J. M. - Abstract:
- Abstract : A manganese porphyrin–α-cyclodextrin conjugate was designed as an artificial clamp-like enzyme to catalyze the epoxidation of cis -polybutadiene with trans -epoxide preference. Abstract : We describe a manganese porphyrin–α-cyclodextrin conjugate as a catalyst for the epoxidation of cis -polybutadiene with trans -epoxide preference, which is a reverse stereoselectivity as compared to normal porphyrin catalysts. A clamp-like mechanism is proposed based on a combination of circular dichroism analysis, molecular modeling, and a series of epoxidation experiments.
- Is Part Of:
- Chemical communications. Volume 54:Issue 44(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 44(2018)
- Issue Display:
- Volume 54, Issue 44 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 44
- Issue Sort Value:
- 2018-0054-0044-0000
- Page Start:
- 5586
- Page End:
- 5589
- Publication Date:
- 2018-05-16
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc02320d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 6948.xml