A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity. Issue 41 (3rd May 2018)
- Record Type:
- Journal Article
- Title:
- A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity. Issue 41 (3rd May 2018)
- Main Title:
- A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity
- Authors:
- Ando, Naoki
Kushida, Tomokatsu
Yamaguchi, Shigehiro - Abstract:
- Abstract : Planarization of B -phenyldibenzo[ b, f ]borepin allows π-expansion across the B -phenyl group and makes this scaffold a useful electron-accepting unit for donor-π-acceptor type fluorophores. Abstract : A B -phenyldibenzo[ b, f ]borepin planarized with two methylene bridges was synthesized. The structural constraint on the B -phenyl group resulted in a bathochromic shift of the absorption and fluorescence properties as well as enhanced Lewis acidity. A donor–π–acceptor type derivative based on this scaffold exhibited intense fluorescence irrespective of the solvent polarity.
- Is Part Of:
- Chemical communications. Volume 54:Issue 41(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 41(2018)
- Issue Display:
- Volume 54, Issue 41 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 41
- Issue Sort Value:
- 2018-0054-0041-0000
- Page Start:
- 5213
- Page End:
- 5216
- Publication Date:
- 2018-05-03
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc02837k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 6937.xml