Preparation of boron nitride nanosheet-coated carbon fibres and their enhanced antioxidant and microwave-absorbing properties. Issue 32 (16th May 2018)

• Record Type: Journal Article
• Authors: Xu, Zhichao; Chen, Yongjun; Li, Wei; Li, Jianbao; Yu, Hui; Liu, Longyang; Wu, Gaolong; Yang, Tao; Luo, Lijie
• Is Part Of: RSC advances. Volume 8:Issue 32(2018)
• Page Start: 17944
• Page End: 17949
• Publication Date: 2018-05-16
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c8ra02017e
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The coating of BN nanosheets on carbon fibers could enhance the anti-oxidation and microwave absorbing properties of carbon fibers significantly. Abstract : In this study, annealing carbon fibres with boron and FeCl3 ·6H2 O at elevated temperatures was demonstrated as a novel route to coat carbon fibres with boron nitride (BN) nanosheets. The effect of annealing temperature on the thickness and microstructure of BN coating was investigated. Results showed that BN coating hardly formed at 1000 °C, and uniform BN coating was achieved at 1100 °C and 1200 °C. However, further increasing the temperature to 1250 °C triggered the formation of discretely distributed BN particles on the surface of the BN coating in addition to the formation of a uniform BN coating. The BN coating and particles were constructed by numerous BN nanosheets with a bending and crumpling morphology. The thickness of the BN coating increased with increasing annealing temperature. The oxidation resistance of the carbon fibres dramatically enhanced after BN nanosheets were coated onto the carbon fibre surface. Moreover, given the low dielectric loss tangent of BN, the BN coating can improve the impedance matching of carbon fibres and enhance the microwave-absorbing property of carbon fibres significantly.