Liquid-phase oxidation of alkanes with molecular oxygen catalyzed by high valent iron-based perovskite. Issue 50 (23rd April 2018)

• Record Type: Journal Article
• Authors: Shibata, Satomi; Sugahara, Kosei; Kamata, Keigo; Hara, Michikazu
• Is Part Of: Chemical communications. Volume 54:Issue 50(2018)
• Page Start: 6772
• Page End: 6775
• Publication Date: 2018-04-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc02185f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A hexagonal BaFeO3− δ perovskite catalyst containing high valent iron species exhibits high catalytic performance for the aerobic oxidation of alkanes without the need for additives. Abstract : Hexagonal BaFeO3− δ containing high valent iron species acted as an efficient heterogeneous catalyst for the aerobic oxidation of alkanes without the need for additives. The activity of BaFeO3− δ was much higher than that of typical Fe 3+ /Fe 2+ -containing iron oxide-based catalysts, and the recovered catalyst could be reused without significant loss of catalytic performance.