Cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes via cyano migration: synthesis of trifluoromethylthiolated acrylonitriles. Issue 50 (28th March 2018)
- Record Type:
- Journal Article
- Title:
- Cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes via cyano migration: synthesis of trifluoromethylthiolated acrylonitriles. Issue 50 (28th March 2018)
- Main Title:
- Cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes via cyano migration: synthesis of trifluoromethylthiolated acrylonitriles
- Authors:
- Ji, Meishan
Yu, Jiajia
Zhu, Chen - Abstract:
- Abstract : Herein a novel, elusive cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes by means of intramolecular distal cyano migration is reported. Abstract : Herein a novel, elusive cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes is reported. Taking advantage of the intramolecular cyano migration strategy, the reaction proceeds stereoselectively to deliver E -olefinic products. A variety of tetrasubstituted trifluoromethylthiolated acrylonitriles are afforded in modest to good yields.
- Is Part Of:
- Chemical communications. Volume 54:Issue 50(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 50(2018)
- Issue Display:
- Volume 54, Issue 50 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 50
- Issue Sort Value:
- 2018-0054-0050-0000
- Page Start:
- 6812
- Page End:
- 6815
- Publication Date:
- 2018-03-28
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc01189c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 6945.xml