A cyano-bridged Cu(i)-based organic framework coupled with the C–C bond cleavage of acetonitrile for selective and sensitive sensing of Fe3+ ions. Issue 20 (30th April 2018)

• Record Type: Journal Article
• Authors: Gai, Yanli; Zhao, Xueyan; Chen, Yan; Yang, Silei; Xia, Xinshu; Liu, Shan; Wan, Xiuyan; Xiong, Kecai
• Is Part Of: Dalton transactions. Volume 47:Issue 20(2018)
• Page Start: 6888
• Page End: 6892
• Publication Date: 2018-04-30
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt00979a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A novel cyano-bridged Cu(i )-based organic framework, in which all cyano anions were generated in situ from the C–C bond cleavage of acetonitrile, exhibits a highly selective and sensitive sensing for Fe 3+ ions. Abstract : A cyano-bridged Cu(i ) organic framework based on [Cu6 (CN)6 ] n was synthesized, in which cyano anions were generated in situ from the C–C bond cleavage of acetonitrile. The as-synthesized compound displays orange-red luminescence and is further proven to be a promising Fe 3+ luminescent sensor with high selectivity and sensitivity.