Multinuclear solid-state NMR study: a powerful tool for understanding the structure of ZnO hybrid nanoparticles. Issue 18 (25th April 2018)

• Record Type: Journal Article
• Authors: Spataro, Grégory; Champouret, Yohan; Florian, Pierre; Coppel, Yannik; Kahn, Myrtil L.
• Is Part Of: Physical chemistry chemical physics. Volume 20:Issue 18(2018)
• Page Start: 12413
• Page End: 12421
• Publication Date: 2018-04-25
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c8cp01096j
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Characterization of hybrid materials is crucial for gaining an in-depth understanding of nano-objects. Abstract : Characterization of hybrid materials is crucial for gaining an in-depth understanding of nano-objects. Here, it is evidenced that the use of multinuclear 1 H, 2 H, 13 C, 15 N, 67 Zn and 17 O MAS NMR spectroscopy is a very powerful approach to acquire both structural and dynamic information on hybrid ZnO nanomaterials prepared from an organometallic approach. Not only is the coordination mode of the organic part onto the inorganic surface evidenced but also important information about the dynamics of the organic capping molecules and some particularities of the nanocrystal structure itself are obtained.