Enhancing radical molecular beams by skimmer cooling. Issue 17 (16th April 2018)

• Record Type: Journal Article
• Authors: Wu, Hao; Reens, David; Langen, Tim; Shagam, Yuval; Fontecha, Daniela; Ye, Jun
• Is Part Of: Physical chemistry chemical physics. Volume 20:Issue 17(2018)
• Page Start: 11615
• Page End: 11621
• Publication Date: 2018-04-16
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c8cp00962g
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : A supersonic beam source has been a key component in many experiments that rely on high molecular densities and cold temperatures. In this work, skimmer cooling is shown to enable significant gains in density for a supersonic beam with entrained species such as hydroxyl radicals. Abstract : A high-intensity supersonic beam source has been a key component in studies of molecular collisions, molecule–surface interaction, chemical reactions, and precision spectroscopy. However, the molecular density available for experiments in a downstream science chamber is limited by skimmer clogging, which constrains the separation between a valve and a skimmer to at least several hundred nozzle diameters. A recent experiment ( Sci. Adv., 2017, 3, e1602258) has introduced a new strategy to address this challenge: when a skimmer is cooled to a temperature below the freezing point of the carrier gas, skimmer clogging can be effectively suppressed. We go beyond this proof-of-principle work in several key ways. Firstly, we apply the skimmer cooling approach to discharge-produced radical and metastable beams entrained in a carrier gas. We also identify two different processes for skimmer clogging mitigation—shockwave suppression at temperatures around the carrier gas freezing point and diffusive clogging at even lower temperatures. With the carrier clogging removed, we now fully optimize the production of entrained species such as hydroxyl radicals, resulting in a gain of 30 in density over the best commercial devices. The gain arises from both clogging mitigation and favorable geometry with a much shorter valve–skimmer distance.