Synthesis and characterization of three hetero-dinuclear complexes with CuO2M cores (M = Na, Hg): Exploration of their phenoxazinone synthase mimicking activity. (1st August 2018)

• Record Type: Journal Article
• Authors: Roy, Sourav; Drew, Michael G.B.; Chattopadhyay, Shouvik
• Is Part Of: Polyhedron. Volume 150(2018)
• Page Start: 28
• Page End: 34
• Publication Date: 2018-08-01
• Subjects: Hetero-dinuclear complex -- Schiff base ligand -- Copper -- Sodium -- Phenoxazinone synthase mimicking activity; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2018.04.018
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical abstract: Phenoxazinone synthase mimicking activities have been investigated in hetero-dinuclear copper(II)/sodium and copper(II)/mercury(II) complexes with N2 O4 donor compartmental Schiff bases. Abstract: Three new hetero-dinuclear complexes, [CuL 1 Na(NCS)]·0.5H2 O (1 ), [CuL 1 Na(OClO3 )]·0.25H2 O (2 ) and [CuL 2 HgCl2 ] (3 ) {where H2 L 1 = N, N′-bis(3-ethoxysalicylidene)-2, 2-dimethylpropane-1, 3-diamine and H2 L 2 = N, N′-bis(3-methoxysalicylidene)-2, 2-dimethylpropane-1, 3-diamine] are N2 O4 donor compartmental Schiff bases} have been synthesized and characterized. The phenoxazinone synthase mimicking activity of each complex in acetonitrile has been investigated with the model substrate o -aminophenol.