Glassy Polymer Networks: Photopolymerized Triazole‐Based Glassy Polymer Networks with Superior Tensile Toughness (Adv. Funct. Mater. 22/2018). (May 2018)

• Record Type: Journal Article
• Authors: Song, Han Byul; Baranek, Austin; Worrell, Brady T.; Cook, Wayne D.; Bowman, Christopher N.
• Is Part Of: Advanced functional materials. Volume 28:Number 22(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-05
• Subjects: additive manufacturing -- "click" chemistry -- ductile thermosets -- photopolymerizations -- photopolymers; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201870146
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract : Tough, ductile photopolymer networks are developed via two independent photo‐"click" reactions in article number1801095 . Christopher N. Bowman and co‐workers specifically use in situ formation of triazoles via the photoinitiated copper‐catalyzed azide–alkyne cycloaddition and photo‐copolymerization of thiol‐ene monomers containing triazoles. These photocurable triazole‐based crosslinked networks present preeminent shape‐memory recovery attributes and the capacity for large tensile deformation in the glassy state.