Lead sorption by biochar produced from digestates: Consequences of chemical modification and washing. (1st August 2018)

• Record Type: Journal Article
• Authors: Wongrod, Suchanya; Simon, Stéphane; Guibaud, Gilles; Lens, Piet N.L.; Pechaud, Yoan; Huguenot, David; van Hullebusch, Eric D.
• Is Part Of: Journal of environmental management. Volume 219(2018)
• Page Start: 277
• Page End: 284
• Publication Date: 2018-08-01
• Subjects: Biochar -- Digestate -- Sorption -- Organic sludge -- Lead; Environmental policy -- Periodicals; Environmental management -- Periodicals; Environment -- Periodicals; Ecology -- Periodicals; 363.705
• DOI: 10.1016/j.jenvman.2018.04.108
• Languages: English
• ISSNs: 0301-4797

Abstract

Abstract: The main objectives of this work are to investigate the consequences of different chemical treatments ( i.e. potassium hydroxide (KOH) and hydrogen peroxide (H2 O2 )) and the effect of biochar washing on the Pb sorption capacity. Biochars derived from sewage sludge digestate and the organic fraction of municipal solid waste digestate were separately modified with 2 M KOH or 10% H2 O2 followed by semi-continuous or continuous washing with ultrapure water using batch or a column reactor, respectively. The results showed that the Pb adsorption capacity could be enhanced by chemical treatment of sludge-based biochar. Indeed, for municipal solid waste biochar, the Pb maximum sorption capacity was improved from 73 mg g −1 for unmodified biochar to 90 mg g −1 and 106 mg g −1 after H2 O2 and KOH treatment, respectively. In the case of sewage sludge biochar, it increased from 6.5 mg g −1 (unmodified biochar) to 25 mg g −1 for H2 O2 treatment. The sorption capacity was not determined after KOH treatment, since the Langmuir model did not fit the experimental data. The study also highlights that insufficient washing after KOH treatment can strongly hinder Pb sorption due to the release of organic matter from the modified biochar. This organic matter may interact in solution with Pb, resulting in an inhibition of its sorption onto the biochar surface. Continuous column-washing of modified biochars was able to correct this issue, highlighting the importance of implementing a proper treated biochar washing procedure. Graphical abstract: Highlights: Chemical treatment (KOH or H2 O2 ) of biochars significantly enhanced Pb sorption. Biochar can release inorganic/organic compounds that hinder Pb sorption. Suitable continuous washing is required to avoid biases in Pb sorption studies. Continuous column washing of the KOH biochar induced a better Pb sorption ability.