Direct Allylation of Active Methylene Compounds with Allylic Alcohols by Use of Palladium/Phosphine‐Borane Catalyst System. Issue 10 (10th April 2018)

• Record Type: Journal Article
• Authors: Shimizu, Aika; Hirata, Goki; Onodera, Gen; Kimura, Masanari
• Is Part Of: Advanced synthesis & catalysis. Volume 360:Issue 10(2018)
• Page Start: 1954
• Page End: 1960
• Publication Date: 2018-04-10
• Subjects: palladium -- phosphine-borane -- allylation -- allylic alcohol -- active methylene; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201800187
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: The C−C bond formation between active methylene compounds and allylic alcohols has been newly developed by using a palladium complex as a catalyst together with a phosphine‐borane ligand. The best phosphine‐borane ligand for this direct allylation has been revealed to be Ph2 P(CH2 )4 (9‐BBN) to produce a variety of desirable allylated products in high yields. Abstract :