Bis(zinc porphyrin) as a CD-sensitive bidentate host molecule: direct determination of absolute configuration of mono-alcohols. Issue 55 (12th June 2015)

• Record Type: Journal Article
• Authors: Hayashi, Satoshi; Yotsukura, Miku; Noji, Masahiro; Takanami, Toshikatsu
• Is Part Of: Chemical communications. Volume 51:Issue 55(2015)
• Page Start: 11068
• Page End: 11071
• Publication Date: 2015-06-12
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc03303a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A facile and direct protocol to determine the absolute configurations of chiral mono-alcohols without analyte derivatization can now be realized using a novel circular dichroic (CD)-sensitive bis(zinc porphyrin)BP1 host system. Abstract : A facile and direct protocol to determine the absolute configurations of chiral mono-alcohols without analyte derivatization can now be realized using a novel circular dichroic (CD)-sensitive bis(zinc porphyrin)BP1 host system. The binding of mono-alcohols toBP1 should be greatly enhanced by the simultaneous double coordination of the hydroxyl group to the two central metals of the porphyrin subunits.