Proton conduction in Mo(vi)-based metallo-supramolecular polymers. Issue 55 (5th June 2015)

• Record Type: Journal Article
• Authors: Pandey, Rakesh K.; Delwar Hossain, Md.; Chakraborty, Chanchal; Moriyama, Satoshi; Higuchi, Masayoshi
• Is Part Of: Chemical communications. Volume 51:Issue 55(2015)
• Page Start: 11012
• Page End: 11014
• Publication Date: 2015-06-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc03634h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : High proton conduction was observed in a Mo(vi )-based metallo-supramolecular polymer with carboxylic acids at 95%RH. The integration of OH groups into the polymer was analysed using FTIR spectroscopy and found to be crucial for the proton transport in the polymer. Abstract : High proton conduction (8.5 × 10 −2 mS cm −1 ) was observed in a Mo(vi )-based metallo-supramolecular polymer with carboxylic acids at 95%RH. The integration of OH groups into the polymer was analysed using FTIR spectroscopy and found to be crucial for the proton transport in the polymer.