Degradation under composting conditions of lysine-modified polyurethane based on PCL obtained by lipase biocatalysis. (June 2018)

• Record Type: Journal Article
• Authors: Arrieta, Marina P.; Barrera Rivera, Karla A.; Salgado, Castor; Martínez Richa, Antonio; López, Daniel; Peponi, Laura
• Is Part Of: Polymer degradation and stability. Volume 152(2018)
• Page Start: 139
• Page End: 146
• Publication Date: 2018-06
• Subjects: PCL -- Polyurethane -- Biocatalysis -- Lipase -- l-lysine -- Biodegradable; Polymers -- Deterioration -- Periodicals; Stabilizing agents -- Periodicals; Polymères -- Dégradation -- Périodiques; Stabilisants -- Périodiques; 668.9
• DOI: 10.1016/j.polymdegradstab.2018.04.010
• Languages: English
• ISSNs: 0141-3910

Abstract

Abstract: Enzymatic polymerization has a large potential as an environmentally friendly synthetic process. Lipase is a renewable catalyst with high catalytic activity from which it is possible to develop a versatile method for the production of sustainable polyurethanes. In this work oligomeric PCL-diol was synthesized using biocatalysis with immobilized Yarrowia lipolytica lipase (YLL) and diethyleneglycol as initiator. Then, two different linear polyurethanes were prepared. One was obtained directly from the previous synthesized PCL-diol and hexamethylene diisocyanate, named PU, and the other one has been obtained by incorporatingl -lysine amino acid as end group (lys-PU). PU and lys-PU disintegration under composting conditions was evaluated. The influence of the presence ofl -lysine on the disintegration performance of PU was studied by evaluating the disintegration degree, monitoring the weight loss. Structural and morphological changes were followed by Fourier transformed infrared spectroscopy (FTIR) and by scanning electron microscopy (SEM). Graphical abstract: Highlights: PCL-diol was enzimatically synthesized by immobilized Yarrowia lipolytica lipase. PCL based polyurethane was modified withl -lysine as end group. Polyurethanes were disintegrated in compost in less than two month. Amino acid chain extender based polyurethane showed higher signs of disintegration.