A supramolecular approach towards strong and tough polymer nanocomposite fibers. Issue 19 (14th March 2018)

• Record Type: Journal Article
• Authors: Zhao, Xiaojuan; Zheng, Hongzhi; Qu, Dan; Jiang, Haijing; Fan, Wei; Sun, Yuyuan; Xu, Yan
• Is Part Of: RSC advances. Volume 8:Issue 19(2018)
• Page Start: 10361
• Page End: 10366
• Publication Date: 2018-03-14
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c8ra01066h
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Strong, tough and flexible polymer nanocomposite fibers can be approached by electrospinning of supramolecular ensemble of CNT–AIE–CNC/PVA in an aqueous system, which could be used for sensing. Abstract : Polymer nanocomposite fibers are important one-dimensional nanomaterials that hold promising potential in a broad range of technological applications. It is, however, challenging to organize advanced polymer nanocomposite fibers with sufficient mechanical properties and flexibility. Here, we demonstrate that strong, tough and flexible polymer nanocomposite fibers can be approached by electrospinning of a supramolecular ensemble of dissimilar and complementary components including flexible multiwalled carbon nanotubes (CNT), and stiff cellulose nanocrystals (CNC) in an aqueous poly(vinyl alcohol) (PVA) system. CNT and CNC are bridged by a water-soluble aggregation-induced-emission (AIE) molecule that forms π–π stacking with CNT via its conjugated chains, and electrostatic attraction with CNC through its positive charges leading to a soluble CNT–AIE–CNC ensemble, which further assembles with PVA through hydrogen bonds. A high level of ordering of the nanoscale building blocks combined with hydrogen bonding leads to a more efficient stress transfer path between the reinforcing unit and the polymer. The nanocomposite fiber mat is capable of selective detection of nitroaromatic explosives.