Puddles – A trigger for heterogeneous chemical influx into the unsaturated zone. (September 2015)

• Record Type: Journal Article
• Authors: Zentner, Eitan; Weisbrod, Noam; Gerstl, Zev; Gasser, Guy; Ronen, Daniel
• Is Part Of: Chemosphere. Volume 134(2015)
• Page Start: 217
• Page End: 223
• Publication Date: 2015-09
• Subjects: ACN acetonitrile -- CAF caffeine -- CBZ carbamazepine -- DOC dissolved organic carbon -- EC electrical conductivity -- HCBZ 10-hydroxy-10, 11-dihydrocarbamazepine -- ODV O-desmethylvenlafaxine -- PPCPs pharmaceuticals and personal care products -- SMX sulfamethoxazole -- TSE treated sewage effluent -- VZ vadose zone -- VLF venlafaxine; Heterogeneous influx -- PPCPs -- Sewage effluents; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2015.04.061
• Languages: English
• ISSNs: 0045-6535

Abstract

Highlights: Variability of chemicals in puddles linked to evapotranspiration and degradation. Increases noted in EC, chloride, DOC and CBZ and decreases in nitrate and CAF. This variability results in heterogeneous influx of solutes into the vadose zone. Abstract: Spatial heterogeneity in the chemical concentration of interstitial water in the vadose zone was previously observed under apparently homogeneous surface conditions on two leveled fields sprinkler irrigated with treated sewage effluents on the phreatic Coastal Plain aquifer of Israel. This phenomenon greatly hampers the monitoring of groundwater quality. In this study we report on the presence of puddles of different size and shape that were sporadically observed in these fields. Temporal variability noted in the concentration of treated sewage effluents components in the puddles were considered to be related to evapotranspiration and degradation. For example: increases in the electrical conductivity (up to 1.32 mS/cm), and in the concentrations of chloride (up to 521 mg/L), dissolved organic carbon (up to 28.4 mg/L), and carbamazepine (up to 780 ng/L) and decreases in the concentrations of nitrate (up to 20.1 mg/L) and caffeine (3396 ng/L). Variable trends in concentration were observed for sulfamethoxazole, venlafaxine, 10-hydroxy-10, 11-dihydrocarbamazepine and o -desmethylvenlafaxine. The presence of puddles was not necessarily related to areas with high irrigation water input. It is postulated that the continuous chemical variability in the puddles, whose location and size are also variable, determine a heterogeneous influx of solutes into the soil and subsequently into the vadose zone.