Facile preparation of porous carbon nanomaterials for robust supercapacitors. Issue 9 (12th December 2017)

• Record Type: Journal Article
• Authors: Zhang, Peng; Xie, Shilei; Qiu, Yongfu; Jiao, Yuanqi; Ji, Chuanwei; Li, Yangping; Fan, Hongbo; Lu, Xihong
• Is Part Of: Journal of materials research. Volume 33:Issue 9(2018)
• Page Start: 1142
• Page End: 1154
• Publication Date: 2017-12-12
• Subjects: nanostructure, -- hydrothermal, -- energy storage; Materials -- Research -- Periodicals; 620.1105
• DOI: 10.1557/jmr.2017.447
• Languages: English
• ISSNs: 0884-2914

Abstract

Abstract: Abstract : Porous carbon nanomaterials with significant capacitive performance were successfully prepared through a simple two-step process of thermal-polymerization and carbonization without an additional template. As a result, the as-prepared porous carbon nanomaterials of sample-A and sample-B exhibited an amorphous phase with low graphitization. And sample-A showed a moderate specific surface area of 476.39 m 2 /g, larger than that of sample-B (280.94 m 2 /g). The relatively high mass specific capacitance of 205.1 F/g at a scan rate of 5 mV/s and 211 F/g at a current density of 4 A/g was obtained by sample-A, which are higher than those of sample-B (82.6 F/g at 5 mV/s and 78.6 F/g at 4 A/g). Sample-A also showed excellent conductivity and superior cyclic stability with 94.19% capacitance retention after 5000 cycles, which are also higher than those of sample-B. This work proposed a cost-effective, green, and promising strategy for the large-scale preparation of porous carbon nanomaterial electrodes.