The reaction of fluorine atoms with methanol: yield of CH3O/CH2OH and rate constant of the reactions CH3O + CH3O and CH3O + HO2. Issue 16 (15th November 2017)

• Record Type: Journal Article
• Authors: Assaf, Emmanuel; Schoemaecker, Coralie; Vereecken, Luc; Fittschen, Christa
• Is Part Of: Physical chemistry chemical physics. Volume 20:Issue 16(2018)
• Page Start: 10660
• Page End: 10670
• Publication Date: 2017-11-15
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c7cp05770a
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Measurement and theory of CH3 O + HO2 and CH3 O + CH3 O reactions, product yields for F + CH3 OH. Abstract : Xenondifluoride, XeF2, has been photolysed in the presence of methanol, CH3 OH. Two reaction pathways are possible: F + CH3 OH → CH2 OH + HF and F + CH3 OH → CH3 O + HF. Both products, CH2 OH and CH3 O, will be converted to HO2 in the presence of O2 . The rate constants for the reaction of both radicals with O2 differ by more than 3 orders of magnitude, which allows an unequivocal distinction between the two reactions when measuring HO2 concentrations in the presence of different O2 concentrations. The following yields have then been determined from time-resolved HO2 profiles: ϕ CH2 OH = (0.497 ± 0.013) and ϕ CH3 O = (0.503 ± 0.013). Experiments under low O2 concentrations lead to reaction mixtures containing nearly equal amounts of HO2 (converted from the first reaction) and CH3 O (from the second reaction). The subsequent HO2 decays are very sensitive to the rate constants of the reaction between these two radicals and the following rate constants have been obtained: k (CH3 O + CH3 O) = (7.0 ± 1.4) × 10 −11 cm 3 s −1 and k (CH3 O + HO2 ) = (1.1 ± 0.2) × 10 −10 cm 3 s −1 . The latter reaction has also been theoretically investigated on the CCSD(T)//M06-2X/aug-cc-pVTZ level of theory and CH3 OH + O2 have been identified as the main products. Using μVTST, a virtually pressure independent rate constant of k (CH3 O + HO2 ) = 4.7 × 10 −11 cm 3 s −1 has been obtained, in good agreement with the experiment.