Enhanced redox activity of a hollow conjugated microporous polymer through the generation of carbonyl groups by carbonylative Sonogashira coupling. Issue 15 (28th March 2018)

• Record Type: Journal Article
• Authors: Choi, Jaewon; Ko, Ju Hong; Kang, Chang Wan; Lee, Sang Moon; Kim, Hae Jin; Ko, Yoon-Joo; Yang, MinHo; Son, Seung Uk
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 15(2018)
• Page Start: 6233
• Page End: 6237
• Publication Date: 2018-03-28
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8ta01379a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : The carbonylative Sonogashira coupling reaction enhanced the redox activity of a hollow conjugated microporous polymer. Abstract : Redox active 1, 4-bis(3-phenylpropynoyl)benzene moieties were incorporated into a hollow conjugated microporous polymer via carbonylative Sonogashira coupling of 1, 3, 5-triethynylbenzene with 1, 4-diiodobenzene in the presence of carbon monoxide. The resultant redox active material showed enhanced energy storage performance for pseudocapacitors.