Gemini‐type cationic surfactant‐directed synthesis of hollow ZSM‐5 zeolite with intracrystalline mesopores and its application in the hydroxylation of phenol. Issue 5 (11th December 2017)

• Record Type: Journal Article
• Authors: Shen, Yu; Wang, Fumin; Han, Zongzhuang; Zhang, Xubin
• Is Part Of: Journal of chemical technology & biotechnology. Volume 93:Issue 5(2018)
• Page Start: 1347
• Page End: 1358
• Publication Date: 2017-12-11
• Subjects: ZSM‐5 -- hollow structure -- intracrystalline mesopores -- phenol hydroxylation -- dihydroxybenzenes; Biotechnology -- Periodicals; Chemistry, Technical -- Periodicals; Chemical engineering -- Periodicals; Industries -- Environmental aspects -- Periodicals; 660
• DOI: 10.1002/jctb.5501
• Languages: English
• ISSNs: 0268-2575

Abstract

Abstract: BACKGROUND: ZSM‐5 zeolites are of great importance in industrial catalysis. However, the diffusion limitations caused by small pore opening restrict the extent of catalytic conversions over conventional ZSM‐5. Many studies have shown that mass transfer in zeolite channels can be improved by controlling the morphology or creating additional mesoporosity. Here, the catalytic performance is further improved by the creation of hollow structure and intracrystalline mesopores in ZSM‐5 zeolite. RESULTS: The characterization results demonstrated that hollow ZSM‐5 with intracrystalline mesopores can be synthesized by using a simple one‐step hydrothermal strategy with a commercial gemini‐type cationic surfactant containing hydrophilic hydroxyl groups. Compared with the Fe‐substituted conventional ZSM‐5, the Fe‐substituted hollow ZSM‐5 with intracrystalline mesopores show remarkably enhanced catalytic performance in the hydroxylation of phenol. About 52.2% conversion of phenol can be obtained with almost 96.8% selectivity to dihydroxybenzenes. The catalytic activity remained almost unchanged after five cycles. CONCLUSION: The newly created hollow structure and intracrystalline mesopores in ZSM‐5 zeolite showed enhanced catalytic activity and reusability for the hydroxylation of phenol, which is higher than most reported systems. The prepared catalyst is a promising alternative material for the hydroxylation of phenol. © 2017 Society of Chemical Industry