Influence of the Processing Parameters on the Dispersion and Coloration Behavior of a Halogenated Copper Phthalocyanine‐Based Masterbatch. Issue 3 (13th June 2016)

• Record Type: Journal Article
• Authors: Buccella, Mauro; Dorigato, Andrea; Rizzola, Fabio; Caldara, Mauro; Fambri, Luca
• Is Part Of: Advances in polymer technology. Volume 37:Issue 3(2018)
• Page Start: 778
• Page End: 785
• Publication Date: 2016-06-13
• Subjects: Coloration behavior -- Dispersion -- Processing parameters; Plastics -- Periodicals; Polymers -- Periodicals; 668.9
• DOI: 10.1002/adv.21721
• Languages: English
• ISSNs: 0730-6679

Abstract

Abstract: A monodispersed green masterbatch was produced through an industrial extrusion process, by mixing a commercial Polyamide 6 matrix (PA6) with a halogenated copper phthalocyanine green pigment. The production process was investigated and optimized in order to improve the pigment dispersion, reducing the clogging power and increasing the color strength of the resulting products. The compounding process based on three extrusions without filtration led to a filter pressure value (FPV) reduction of about 84% and a relative color strength (RCS) increase of about 50% with respect to the standard production process (i.e single extrusion). The thermal stability of the prepared compounds was evaluated by rheological test, viscosity measurements, and end group analysis, and it was found that a triple extrusion without filtration promoted thermo‐oxidative matrix degradation. However, the same processing conditions led to a significant reduction of the production waste, increasing the productivity and the quality of the final product.