Preparation of 4‐(4‐hydroxyphenoxy)phenol diglycidyl ether with improved toughness behavior. Issue 28 (31st March 2018)

• Record Type: Journal Article
• Authors: Liu, Caizhao; Sun, Mingming; Zhang, Bin; Zhang, Xugang; Li, Jianhui; Xue, Gang; Wang, Lei; Zhao, Ming; Song, Caiyu; Li, Qili; Jia, Jingxia
• Is Part Of: Journal of applied polymer science. Volume 135:Issue 28(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-03-31
• Subjects: differential scanning calorimetry (DSC) -- glass transition -- kinetics -- resins -- thermogravimetric analysis (TGA); Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.46458
• Languages: English
• ISSNs: 0021-8995

Abstract

ABSTRACT: A high‐performance difunctional epoxy resin, 4‐(4‐hydroxyphenoxy)phenol diglycidyl ether (DHPOP), was synthesized by a two‐step method. The curing behavior of DHPOP was investigated by nonisothermal differential scanning calorimetry method and the curing kinetics results revealed that the introduction of ether linkage could improve the activity of epoxy groups, leading to a lower curing temperature and apparent activation energy compared with that of the commercial bisphenol‐A diglycidyl ether (DGEBA). A series of copolymers were then prepared by varying the mass ratio of DHPOP and DGEBA, which were cured with 4, 4′‐diaminodiphenyl methane. The effect of DHPOP contents on thermal and mechanical properties and fracture morphology was studied. As expected, with the increase of DHPOP in the network, the impact strength and char yield were significantly enhanced, while the glass transition temperature ( Tg ) remained unchanged because of the increase of crosslink density. The excellent toughness endows the DHPOP with the promising potential for the application as high‐performance resin matrix. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2018, 135, 46458. Abstract :