A three-dimensional cubic halogen-bonded network. Issue 32 (3rd April 2018)

• Record Type: Journal Article
• Authors: Pfrunder, Michael C.; Brock, Aidan J.; Brown, Joshua J.; Grosjean, Arnaud; Ward, John; McMurtrie, John C.; Clegg, Jack K.
• Is Part Of: Chemical communications. Volume 54:Issue 32(2018)
• Page Start: 3974
• Page End: 3976
• Publication Date: 2018-04-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc02178c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The rational, deliberate design of supramolecular architectures is of great importance for the discovery of complex materials. Abstract : The rational, deliberate design of supramolecular architectures is of great importance for the discovery of complex materials. A three-dimensional cubic halogen-bonded network has been prepared by combination of an octahedral metal-containing halogen bond acceptor and a linear ditopic donor. This material displays α-Popcu topology and is seven-fold interpenetrated. This is the first neutral, metal-containing three-dimensional halogen-bonded network to be reported.