Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. (26th March 2018)

• Record Type: Journal Article
• Authors: Ghorpade, Seema Arun; Sawant, Dinesh Nanaji; Renn, Dominik; Zernickel, Anna; Du, Weiyuan; Sekar, Nagaiyan; Eppinger, Jörg
• Is Part Of: New journal of chemistry. Volume 42:Number 8(2018)
• Page Start: 6210
• Page End: 6214
• Publication Date: 2018-03-26
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c8nj00660a
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Allylic arylation using 0.002 mol% of a Bedford-type palladacycle catalyst is described under mild reaction conditions. Abstract : Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol% of a Bedford-type palladacycle catalyst is described. The developed methodology is applicable for a wide range of cinnamyl acetates furnishing excellent yields of up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under an air atmosphere.