Liquid phase separation phenomena in Al2.2CrCuFeNi2 HEA. (June 2018)

• Record Type: Journal Article
• Authors: Munitz, A.; Samuha, S.; Brosh, E.; Salhov, S.; Derimow, N.; Abbaschian, R.
• Is Part Of: Intermetallics. Volume 97(2018:Jun.)
• Page Start: 77
• Page End: 84
• Publication Date: 2018-06
• Subjects: Stable miscibility gap -- Constitutional liquid phase separation -- Two liquids -- Rosette structure -- Sigma phase -- Spinodal decomposition; Intermetallic compounds -- Metallography -- Periodicals; Metallic glasses -- Periodicals; Composés intermétalliques -- Métallographie -- Périodiques; 669.94
• DOI: 10.1016/j.intermet.2018.04.004
• Languages: English
• ISSNs: 0966-9795

Abstract

Abstract: Vacuum arc melting was used to produce buttons of Al2.2 CrCuFeNi2 HEA. High resolution scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) capabilities as well as X-ray diffraction (XRD) were used for microstructural characterization. The alloy solidified dendritically with rosette structure of dendritic core (DC) regions composed of at least 3 concentric circles or semicircles with different phases and morphology. First to solidify was found to be a supersaturated solid solution with matrix B2 structure that underwent spinodal decomposition as the alloy cooled during solidification. The B2, matrix which initially contained nanosize cubical disordered BCC precipitates, later changed to nanosize rectangles (2nd circle), and eventually to micron-size elongated non-faceted precipitates. This was followed by the solidification of the residual Cu-rich liquid in the interdendritic (ID) regions, which separated into two liquids (LPS) upon rejection of more solute into the liquid. We term this liquid phase separation as "constitutional LPS" in contrast with thermal LPS that takes place during cooling of stable or metastable monotectic alloys. Nevertheless, the constitutional LPS was not predicted using the existing thermodynamic databases. Highlights: Liquid phase separation, LPS, in Al2.2 CrCuFeNi2 is constitutional activated due to solid rejection into the residual melt. Considerable dendrite growth has taken place which impair the fluid flow causing unique microstructure. . Characteristic microstructure of LPS is spheres of the minority liquid embedded in the microstructure of the other liquid. The Rosset microstructure obtained in Al2.2 CrCuFeNi2 could be explained by constitutional LPS.